Evaluation in late modern English history writing

Die vorliegende Arbeit beschäftigt sich mit der Identifikation und der Klassifikation von evaluativer Lexis in den Werken von britischen Geschichtsschreibern der Spätneuzeit. Im Fokus stehen die von den Historikern im Verlauf von 200 Jahren (ca. 1700-1914) verwendeten sprachlichen Mittel, welche zur Bewertung von historischen Ereignissen und Akteuren eingesetzt werden, und die durch die Mittel realisierten Funktionen. Zentral ist die Betrachtung von Evaluation als linguistischem Mittel der Signifikanzherstellung in neuzeitlicher englischer Geschichtsschreibung. Die Arbeit stützt sich in ihren theoretische Ansätzen u.a. auf das Appraisal Framework (Martin & White 2005) und erweitert dieses, um es unter Einsatz von sowohl korpuslinguistisch-quantitativer als auch qualitativer Methoden auf ein großes Korpus historischer Primärwerke aus dem 18.-19. Jahrhundert anzuwenden. Sie verortet sich sowohl in der historischen/diachronen Diskursforschung als auch in der korpusunterstützten Diskursanalyse (Partington et al. 2013) und liefert eine erste linguistische Beschreibung des historiographischen Registers in der wichtigen Periode seiner allmählichen Verwissenschaftlichung und Institutionalisierung. Indem sie eine interdisziplinäre Perspektive einnimmt, vermittelt diese Arbeit zwischen historischer Theoriebildung und linguistischer Theorie und Methodik.This paper is concerned with the identification and classification of evaluative lexis in the works of British historians of the Late Modern period. The focus is on the linguistic resources used by historians over the course of 200 years (c. 1700-1914) to evaluate historical events and actors, and the functions realised through these resources. Central to the study is the consideration of evaluation as a linguistic means of signaling historical significance in Late Modern English historiography. The work draws on the Appraisal Framework (Martin & White 2005) and extends it in order to apply it to a large corpus of primary historical works from the 18th-19th centuries using both corpus-linguistic-quantitative and qualitative methods. Situating itself in both historical/diachronic discourse research and corpus-assisted discourse analysis (Partington et al. 2013), it provides the first linguistic account of the historiographical register in the pivotal period of its gradual scientification and institutionalisation. By adopting an interdisciplinary perspective, this work mediates between historiographic theorising and linguistic theory and methodology

Predicting the potential of capacitive deionization for the separation of pH‐dependent organic molecules

One of the main steps in the biotechnological production of chemical building blocks, such as, e.g. bio-based succinic acid which is used for lubricants, cosmetics, food, and pharmaceuticals, is the isolation and purification of the target molecule. A new approach to isolate charged, bio-based chemicals is by electrosorption onto carbon surfaces. In contrast to ion exchange, electrosorption does not require additional chemicals for elution and regeneration. However, while the electrosorption of inorganic salts is well understood and in commercial use, the knowledge about electrosorption of weak organic acids including the strong implications of the pH-dependent dissociation and their affinity towards physical adsorption must be expanded. Here, we show a detailed discussion of the main pH-dependent effects determining the achievable charge efficiencies and capacities. An explicit set of equations allows the fast prediction of the named key figures for constant voltage and constant current operation. The calculated and experimental results obtained for the electrosorption of maleic acid show that the potential-free adsorption of differently protonated forms of the organic acid play a dominating role in the process. At pH 8 and a voltage threshold of 1.3 V, charge efficiencies of 25% and capacities around 40 mmol/kg could be reached for a constant current experiment. While this capacity is clearly below that of ion exchange resins, the required carbon materials are inexpensive and energy costs are only about 0.013 €/mol. Therefore, we anticipate that electrosorption has the potential to become an interesting alternative to conventional unit operations for the isolation of charged target molecules

Effect of Prandtl number on heat transport enhancement in Rayleigh-B\'enard convection under geometrical confinement

We study, using direct numerical simulations, the effect of geometrical confinement on heat transport and flow structure in Rayleigh-B\'enard convection in fluids with different Prandtl numbers. Our simulations span over two decades of Prandtl number $Pr$, $0.1 \leq Pr \leq 40$, with the Rayleigh number $Ra$ fixed at $10^8$. The width-to-height aspect ratio $\Gamma$ spans between $0.025$ and $0.25$ while the length-to-height aspect ratio is fixed at one. We first find that for $Pr \geq 0.5$, geometrical confinement can lead to a significant enhancement in heat transport as characterized by the Nusselt number $Nu$. For those cases, $Nu$ is maximal at a certain $\Gamma = \Gamma_{opt}$. It is found that $\Gamma_{opt}$ exhibits a power-law relation with $Pr$ as $\Gamma_{opt}=0.11Pr^{-0.06}$, and the maximal relative enhancement generally increases with $Pr$ over the explored parameter range. As opposed to the situation of $Pr \geq 0.5$, confinement-induced enhancement in $Nu$ is not realized for smaller values of $Pr$, such as $0.1$ and $0.2$. The $Pr$ dependence of the heat transport enhancement can be understood in its relation to the coverage area of the thermal plumes over the thermal boundary layer (BL) where larger coverage is observed for larger $Pr$ due to a smaller thermal diffusivity. We further show that $\Gamma_{opt}$ is closely related to the crossing of thermal and momentum BLs, and find that $Nu$ declines sharply when the thickness ratio of the thermal and momentum BLs exceeds a certain value of about one. In addition, through examining the temporally averaged flow fields and 2D mode decomposition, it is found that for smaller $Pr$ the large-scale circulation is robust against the geometrical confinement of the convection cell.Comment: 25 pages, 11 figures, and 1 table in main tex

Untersammelsdorf Tunnel – Challenges, Special Measures and use of Special Shotcrete for Tunneling in Lacustrine Clay

The 665 m long, twin-track Untersammelsdorf Tunnel is being built in the course of the construction of the Koralmbahn line between Graz and Klagenfurt. The tunnel is located in extremely challenging subsoil conditions consisting of silty to fine sandy lacustrine deposits. The developed tunneling concept provided wide-ranging special underground engineering measures as piling, jet grouting and temporary struts and represents a unique construction method to date. Accordingly, numerous challenges arose in the design phase, which could be verified by carrying out extensive trials and investigations in the preparatory period or for which fallback levels had to be provided for the support system. Please click Additional Files below to see the full abstract

NephroCheck data compared to serum creatinine in various clinical settings

Figure B: TIMP-2 immunofluorescence staining of tubular cells in the urine sediment of patient #2. (TIF 6713 kb

Lithium related deep and shallow acceptors in Li-doped ZnO nanocrystals

This article may be downloaded for personal use only. Any other use requires prior permission of the author and AIP Publishing. This article appeared in Journal of Applied Physics 107, 024311 (2010) and may be found at https://doi.org/10.1063/1.3275889.We study the existence of Li-related shallow and deep acceptor levels in Li-doped ZnO nanocrystals using electron paramagnetic resonance (EPR) and photoluminescence (PL) spectroscopy. ZnO nanocrystals with adjustable Li concentrations between 0% and 12% have been prepared using organometallic precursors and show a significant lowering of the Fermi energy upon doping. The deep Li acceptor with an acceptor energy of 800 meV could be identified in both EPR and PL measurements and is responsible for the yellow luminescence at 2.2 eV. Additionally, a shallow acceptor state at 150 meV above the valence band maximum is made responsible for the observed donor-acceptor pair and free electron-acceptor transitions at 3.235 and 3.301 eV, possibly stemming from the formation of Li-related defect complexes acting as acceptors.DFG, 43659573, SFB 787: Halbleiter - Nanophotonik: Materialien, Modelle, Bauelement

Local charge and spin currents in magnetothermal landscapes

A scannable laser beam is used to generate local thermal gradients in metallic (Co2FeAl) or insulating (Y3Fe5O12) ferromagnetic thin films. We study the resulting local charge and spin currents that arise due to the anomalous Nernst effect (ANE) and the spin Seebeck effect (SSE), respectively. In the local ANE experiments, we detect the voltage in the Co2FeAl thin film plane as a function of the laser spot position and external magnetic field magnitude and orientation. The local SSE effect is detected in a similar fashion by exploiting the inverse spin Hall effect in a Pt layer deposited on top of the Y3Fe5O12. Our findings establish local thermal spin and charge current generation as well as spin caloritronic domain imaging

"What's (the) Matter?", A Show on Elementary Particle Physics with 28 Demonstration Experiments

We present the screenplay of a physics show on particle physics, by the Physikshow of Bonn University. The show is addressed at non-physicists aged 14+ and communicates basic concepts of elementary particle physics including the discovery of the Higgs boson in an entertaining fashion. It is also demonstrates a successful outreach activity heavily relying on the university physics students. This paper is addressed at anybody interested in particle physics and/or show physics. This paper is also addressed at fellow physicists working in outreach, maybe the experiments and our choice of simple explanations will be helpful. Furthermore, we are very interested in related activities elsewhere, in particular also demonstration experiments relevant to particle physics, as often little of this work is published. Our show involves 28 live demonstration experiments. These are presented in an extensive appendix, including photos and technical details. The show is set up as a quest, where 2 students from Bonn with the aid of a caretaker travel back in time to understand the fundamental nature of matter. They visit Rutherford and Geiger in Manchester around 1911, who recount their famous experiment on the nucleus and show how particle detectors work. They travel forward in time to meet Lawrence at Berkeley around 1950, teaching them about the how and why of accelerators. Next, they visit Wu at DESY, Hamburg, around 1980, who explains the strong force. They end up in the LHC tunnel at CERN, Geneva, Switzerland in 2012. Two experimentalists tell them about colliders and our heroes watch live as the Higgs boson is produced and decays. The show was presented in English at Oxford University and University College London, as well as Padua University and ICTP Trieste. It was 1st performed in German at the Deutsche Museum, Bonn (5/'14). The show has eleven speaking parts and involves in total 20 people.Comment: 113 pages, 88 figures. An up to date version of the paper with high resolution pictures can be found at http://www.th.physik.uni-bonn.de/People/dreiner/Downloads/. In v2 the acknowledgements and a citation are correcte

Clarifications on the "Comparison Between SMOS, VUA, ASCAT, and ECMWF Soil Moisture Products Over Four Watersheds in U.S."

In a recent paper, Leroux et al. compared three satellite soil moisture data sets (SMOS, AMSR-E, and ASCAT) and ECMWF forecast soil moisture data to in situ measurements over four watersheds located in the United States. Their conclusions stated that SMOS soil moisture retrievals represent "an improvement [in RMSE] by a factor of 2-3 compared with the other products" and that the ASCAT soil moisture data are "very noisy and unstable." In this clarification, the analysis of Leroux et al. is repeated using a newer version of the ASCAT data and additional metrics are provided. It is shown that the ASCAT retrievals are skillful, although they show some unexpected behavior during summer for two of the watersheds. It is also noted that the improvement of SMOS by a factor of 2-3 mentioned by Leroux et al. is driven by differences in bias and only applies relative to AMSR-E and the ECWMF data in the now obsolete version investigated by Leroux et al